Atomically precise heterostrucutures present chemically interesting active sites for catalysis but are often expensive and/or challenging to synthesize. In this article, we report a synthetic strategy to conformally coating Cu atoms onto the surface of Pd/HyWO3-x by anchoring Cu(I)OtBu to the Brønsted acidic protons of the bronze. It was observed that just 0.2 at.% of Cu was able to increase the catalytic performance of CO2 hydrogenation to CO by 500%. This metal anchoring method enables atom precise modification of the surfaces of metal oxide nanomaterials for catalytic applications, circumventing the need for complex and expensive atomic layer deposition processes.
See full article at Journal of the American Chemical Society.
-
Recent Posts
- A natural way of turning off the carbon dioxide tap, California style
- DIY Eco-Friendly Fertilizer
- Congratulations to Pavani, Geoff, Wei, and co-authors on their publication in Science Advances!
- Congratulations to Joel and co-authors on their publication in Nature Communications!
- Congratulations to Truong and co-authors on their publication in Nano Letters!
Recent Comments
Categories
Header Courtesy of Digital Westex