Surface Frustrated Lewis Pairs (SFLPs) have been implicated in the gas‐phase heterogeneous (photo)catalytic hydrogenation of CO₂ via the cubic form of hydroxylated indium oxide. In their paper, Dr. Wang and co-authors report the room temperature dissociation of molecular hydrogen via SFLPs on the rhombodral form of the catalyst, which is shown to favour the heterolysis over the homolysis reaction pathway.
See full article at Angewandte Chemie.
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